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STABLE CRYSTALLINE CELLULOSE III POLYMORPHS
See also: US Patent Office Full Record

Patent Number: 5322524
Docket Number: 140287
Serial Number: 7758188
Date Patented: 06/21/1994

Agency:

Agricultural Research Service
Issued:
June 21, 1994

Abstract:
The invention is cotton cellulose fiber with its entire crystalline lattice consisting essentially of cellulose III that is highly stable in the presence of water. This fiber has improved resistance to abrasion and increased permeability to chemicals. Cotton cellulose fiber, which may be selected from either yarn, fabric or cotton bolls, is treated with ammonia vapors at about ambient to 140 degrees C and from about 100 psi to 1700 psi for sufficient time to alter the interatomic planar distances, producing the stable crystalline cellulose III polymorph. Crystalline cellulose III can also be immersed in ethylenediamine and then boiled in dimethylformamide to completely convert cellulose III to cellulose IV.

Inventors:
Lawrence Y. Yatsu Timothy A. Calamari, Jr.
USDA, ARS, SRRC USDA, ARS, SRRC
New Orleans, LA New Orleans, LA
(504) 286-4276 (504) 286-4265

Ruth R. Benerito (retired)
USDA, ARS, SRRC
New Orleans, LA

Industry Keywords:

cotton, textile, cellulose, fiber, yarn, chemical finish, cellulose III

 
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