NIOSH Pocket Guide to Chemical Hazards

Boron oxide CAS 1303-86-2
B2O3 RTECS ED7900000
Synonyms & Trade Names
Boric anhydride, Boric oxide, Boron trioxide
DOT ID & Guide
Exposure
Limits
NIOSH REL: TWA 10 mg/m3
OSHA PEL†: TWA 15 mg/m3
IDLH 2000 mg/m3 See: 1303862 Conversion
Physical Description
Colorless, semitransparent lumps or hard, white, odorless crystals.
MW: 69.6
BP: 3380°F
MLT: 842°F
Sol: 3%
VP: 0 mmHg (approx)
IP: 13.50 eV

Sp.Gr: 2.46
Fl.P: NA
UEL: NA
LEL: NA

Noncombustible Solid
Incompatibilities & Reactivities
Water [Note: Reacts slowly with water to form boric acid.]
Measurement Methods
NIOSH 0500
See: NMAM or OSHA Methods
Personal Protection & Sanitation
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: No recommendation

First Aid (See procedures)
Eye: Irrigate immediately
Skin: Water flush promptly
Breathing: Fresh air
Swallow: Medical attention immediately
Important additional information about respirator selection
Respirator Recommendations NIOSH
Up to 50 mg/m3: (APF = 5) Any dust and mist respirator*
Up to 100 mg/m3: (APF = 10) Any dust and mist respirator except single-use and quarter-mask respirators^*/(APF = 10) Any supplied-air respirator*
Up to 250 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode*/(APF = 25) Any powered, air-purifying respirator with a dust and mist filter^*
Up to 500 mg/m3: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter/(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter*/(APF = 50) Any self-contained breathing apparatus with a full facepiece/(APF = 50) Any supplied-air respirator with a full facepiece
Up to 2000 mg/m3: (APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter/Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation, ingestion, skin and/or eye contact
Symptoms Irritation eyes, skin, respiratory system; cough; conjunctivitis; skin erythema (skin redness)
Target Organs Eyes, skin, respiratory system
See also: INTRODUCTION   See ICSC CARD: 0836

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