October 24, 2001
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story tips, please contact the public information
officer at the end of each item at (703) 292-8070.
Editor: Peter West
Contents of this News Tip:
Films such as cell membranes, that allow the passage
of some substances while blocking others are ubiquitous
in nature. Artificial ones, ranging from the filters
in seawater desalination plants to the oxygen-blocking
plastic wrap in your kitchen, are also common.
Now a research team at Northwestern University, supported
by the National Science Foundation (NSF), has developed
a thin-film material with nanometer-sized cavities
that serves as a molecular gatekeeper. The material
can be manipulated to allow the passage of certain
molecules on the basis of size, shape and other properties.
The scientists -- chemists and chemical engineers
Joseph Hupp, SonBinh Nguyen and Randall Snurr -- have
also discovered a means of chemically transforming
molecules within these cavities. They will report
their results in upcoming issues of the European journals
Angewandte Chemie and Advanced Materials.
The technique involves programmed, directed assembly
of nanoscale building blocks, then condensation of
the building blocks into arrays. The tiny cavities
of the array serve as a filter, but in solution the
cavities can also be used to encapsulate catalysts
that chemically transform molecules. According to
the scientists, a logical next step would be to combine
the filtration and catalytic steps. This would allow
conversion of plentiful low-cost hydrocarbon molecules
into valuable complex molecules with potential applications
such as selective drug delivery, synthesis of specialty
chemicals or new types of semiconductors. [Amber
Jones]
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Autumn leaves that light up hillsides also appear
to play a role in regional air quality and climate.
Scientists funded by NSF and the Environmental Protection
Agency and affiliated with the National Center for
Atmospheric Research (NCAR) in Boulder, Colorado,
are measuring levels of chemicals that are emitted
as leaves change color and fall to the ground.
Known as volatile organic compounds (VOCs), the chemicals
have wide-ranging effects: they combine with certain
types of industrial emissions to create smog, and
in some cases play a role in global warming. VOCs
are the source of the scents associated with pine
needles and cut grass, and pose no harm in a natural
setting. But they can react with human-generated nitrogen
oxides in the presence of sunlight to form ground-level
ozone, the major component of smog. The emissions
also have an impact on climate by slowing the rate
at which greenhouse gases are oxidized in the atmosphere.
The research is taking place in northern Michigan,
a location chosen because the state’s abrupt, heavy
frosts are likely to result in high levels of emissions.
[Cheryl Dybas]
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A new Industrial Research and Development Information
System (IRIS) now makes all of NSF's historical data
on industrial R&D;, covering a 45-year period, available
on-line.
The expansive new system provides access to statistics
on industrial R&D; performance across a broad range
of criteria in about 2,500 statistical tables, and
links an on-line interface to historical data. The
data "can be used to assess trends in U.S. R&D; performance
from a variety of perspectives," says a recent Data
Brief from NSF's Division of Science Resources Statistics.
The IRIS system not only provides the detailed R&D;
statistics over four and a half decades within its
historical database, but also provides a glossary
of terms, help files and links to related NSF publications
in R&D.;
IRIS is accessed through a welcome screen that allows
observers to browse tables by survey year or topic,
and also through a "search for data tables" option.
[Bill Noxon]
For IRIS on-line, see: http://www.nsf.gov/sbe/srs/iris/start.htm
NSF is an independent federal agency which supports
fundamental research and education across all fields
of science and engineering, with an annual budget
of about $4.5 billion. NSF funds reach all 50 states,
through grants to about 1,800 universities and institutions
nationwide. Each year, NSF receives about 30,000 competitive
requests for funding, and makes about 10,000 new funding
awards.
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