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geer > 2000 > poster > Nutrient Transport To Biscayne Bay and Water-Quality Trends At Selected Sites In Southern Florida


Nutrient Transport To Biscayne Bay and Water-Quality Trends At Selected Sites In Southern Florida

Poster presented December 2000, at the Greater Everglades Ecosystem Restoration Conference

By A.C.Lietz

[ Disclaimer ]

photo of Miami Canal
Miami Canal at S-26 [larger image]
During the early 1900's, water-management practices were undertaken which eventually resulted in the development of a highly managed hydrologic system which currently exists as a system of levees, pump stations, gated control structures, and water conservation areas in southern Florida. This complex hydrologic system was created for the purposes of flood control, water storage, replenishment of ground-water supplies, and retardation of saltwater intrusion. This man-made system has altered natural hydropatterns and degraded water quality in the Everglades ecosystem.

Plans for restoring the southern Florida and Everglades ecosystems to its predevelopment state requires filling canals, removing levees, and rechanneling canal discharges that currently enter Biscayne Bay. Biscayne Bay, a shallow subtropical estuary along the southeastern coast of Florida, provides an aquatic environment that is habitat to a diverse population of plant and animal species. As a result of agricultural and urban activities, increased nutrient loads in discharges from the east coast canals in southern Florida are a potential threat to the health of Biscayne Bay. An understanding of nutrient transport to Biscayne Bay is needed to assess the ecological health of the bay and to evaluate the water-quality impact of the diverted water to Everglades National Park. Restoring the southern Florida and Everglades ecosystem also requires an understanding of the changes in water quality that have occurred over time.

photo of scientist sampling
Samples Composited In Churn At Bridge Upstream Of S-22 [larger image]
The U. S. Geological Survey, as part of its South Florida Place-Based Studies Program, initiated a project to document and define the concentration, distribution, and transport of nutrients to the bay from the coastal canal network. Water samples were collected from east coast canals in 1996-97 (primarily during the wet season) to determine concentrations of major organic and inorganic nitrogen and phosphorus species. Study results indicate that within the Biscayne Bay watershed, median concentrations of some nitrogen and phosphorus species were highest in selected land-use categories: (1) nitrite plus nitrate in the agricultural land-use category; (2) ammonia, total phosphorus, and orthophosphate in the urban land-use category; and (3) total organic nitrogen in the wetlands category.

Depth-integrated samples were statistically different in total phosphorus concentration than 25 percent of grab samples at 1.0 meter depth and 33 percent of grab samples collected at 0.5 meter depth. No statistically significant differences were found for total nitrogen between grab and depth-integrated samples. Grab samples also were found to be biased low when compared to depth-integrated samples. A simple linear regression analysis was used to develop models for estimating total nitrogen and total phosphorus loads from the east coast canals to Biscayne Bay. Because of the large number of water samples collected over the years (1987-96) and the availability of continuous discharge data, a log-linear model employing a minimum variance unbiased estimator was used to compute total nitrogen and total phosphorus loads for site S-26 at the Miami Canal.
photo of water and vegetation
Outlet on Tamiami Canal in Big Cypress National Preserve [larger image]

Restoring and enhancing the natural ecosystem requires an understanding of how water quality has been affected over time by anthropogenic influences in southern Florida. Two U. S. Geological Survey daily discharge stations, one within the Big Cypress National Preserve (Tamiami Canal - 40 Mile Bend to Monroe) and one near Biscayne Bay (Miami Canal at S-26), were analyzed for long-term (1966-94) trends in water quality to characterize prerestoration water quality and to document changes in water quality over time.

The principal tool used for the water-quality analysis was the Seasonal Kendall Trend (SKT) test, a nonparametric test that compares relative ranks of data values from the same seasons to negate variation caused by seasonality. To discern the anthropogenic influences that have affected water quality over the years, variation caused by discharge also should be negated. This was accomplished by performing the SKT onflow-adjusted concentrations (residuals) from statistically significant concentration/discharge relations developed using linear regression models. Long-term trends were determined at both sites for selected major inorganic constituents and physical characteristics; pH and dissolved oxygen; suspended sediment; nitrogen, phosphorus, and carbon species; trace metals; and bacteriological and biological characteristics.

photo of scientist collecting samples
Samples Collected With Vandorn Sampler At Snapper Creek S-22 [larger image]
Statistically significant (p-value less than 0.10) temporal trends for water-quality constituents at the Miami and Tamiami Canal stations were classified as indicators of either improvement or deterioration in water quality over time. Most downward trends indicate improvement in water quality over time; however, downward trends in pH and dissolved oxygen indicate deterioration over time and the potential for harmful effects for aquatic life. At the Miami Canal station, improvement in water quality was documented by 7 trends and deterioration in water quality was documented by 14 trends. At the Tamiami Canal station, improvement and deterioration in water quality were indicated by 4 and 9 trends, respectively. Median and maximum concentrations at both sites were compared to the State of Florida freshwater standards; most concentrations were within these standards. However, the median concentrations of dissolved oxygen at the Miami and Tamiami Canal stations were 3.3 and 2.7 milligrams per liter, respectively, and did not meet the State freshwater standard of at least 5.0 milligrams per liter. Additionally, the median and maximum concentrations of total ammonia at both sites exceeded the State freshwater standard of 0.02 milligrams per liter.

A. C. Lietz, U. S. Geological Survey, 9100 N.W. 36th Street Suite 107, Miami, FL, 33178, Phone: 305-717-5838, Fax:305-717-5801, alietz@usgs.gov Oral, Water Quality and Water Treatment Technologies

Project Objectives
  • Determine Method For Estimating Loads From Canals To Bay
  • Characterize Nutrient Concentration And Distribution In The East Coast Canals
  • Evaluate Sampling Methods In Order To Document Most Representative Manner Of Sample Collection
  • Determine Long-term Trends at Selected Sites in South Florida

Location Of Sampling Sites
map of sampling site locations
Location of the east coast canal sites and subregions in Miami-Dade County [larger image]


Summary statistics for the estimation of total nitrogen and total phosphorus loads at site S-26 computed by the ESTIMATOR program for water years 1987-96
Water year
Constituent
Maximum monthly mean daily load (tons per day)
Minimum monthly mean daily load (tons per day)
Annual daily load (tons per year)
1987
Total nitrogen

Total phosphorus

0.72

.008

0.011

1.85 x 10-4

78.2

.70

1988
Total nitrogen

Total phosphorus

1.68

.021

.004

6.32 x 10-4

190

2.47

1989
Total nitrogen

Total phosphorus

.54

.007

.00

.00

46.5

.61

1990
Total nitrogen

Total phosphorus

1.01

.012

.00

.00

85.5

1.11

1991
Total nitrogen

Total phosphorus

1.60

.018

.013

2.21 x 10-4

144

1.81

1992
Total nitrogen

Total phosphorus

2.63

.028

.040

6.55 x 10-4

261

2.98

1993
Total nitrogen

Total phosphorus

1.04

.012

.008

1.38 x 10-4

188

2.18

1994
Total nitrogen

Total phosphorus

.77

.008

.018

2.48 x 10-4

127

1.45

1995
Total nitrogen

Total phosphorus

2.00

.019

.00

.00

268

2.71

1996
Total nitrogen

Total phosphorus

1.72

.016

.00

.00

199

2.19


Figure Showing EWI Sampling

illustration of EWI sampling method

Depth-integrated sample collected by use of the
equal-width-increment method. [larger image]


graph of total organic nitrogen concentration

Median Total Organic Nitrogen Concentrations Were Highest In Wetland And Urban Areas [larger image]


graph of nitrate concentration

Median Nitrate Concentrations Were Highest In Agricultural Areas [larger image]


graph of ammonia concentration

Median Concentrations of Total Ammonia Were Highest In Urban Areas [larger image]


graph of total nitrite plus nitrate concentration

Total Nitrite Plus Nitrate Concentrations [larger image]


Location Of Sampling Sites

map of sampling site locations
[larger image]


Tamiami Canal Outlets
map of outlets
map of Station 02288800 Monroe to Carnestown map of Station 02288900 40-Mile Bend to Monroe
map of Station 02289040 Levee 67A to 40-Mile Bend map of Station 02289060 Levee 30 to Levee 67A

Tamiami Canal Outlets (from Price and others, 1998, p. 203).
[click on images to view larger versions]


LOWESS lines of selected major inorganic constituents and other characteristics as a function of time at the Miami Canal station. Smoothness factor is 0.5.

graph of potassium levels over time
[larger image]
graph of silica levels over time
[larger image]
graph of sulfate levels over time
[larger image]
graph of pH levels over time
[larger image]
graph of suspended sediment amounts over time
[larger image]
graph of dissolved solids amounts over time
[larger image]
graph of sodium levels over time
[larger image]
graph of magnesium levels over time
[larger image]
graph of turbidity levels over time
[larger image]
graph of chloride levels over time
[larger image]
graph of dissolved solids amounts over time
[larger image]
graph of specific conductance over time
[larger image]


Summary of Water Quality Indicators Showing Improvement or Deterioration at the Miami and Tamiami Canal Stations Over Time
[Based on trends determined at a p-value of 0.10]
Water-quality constituent
Time period
Trend
Effect on water quality
Miami Canal Station
Chloride
1966-94
Upward
Deterioration
Magnesium
1966-94
Upward
Deterioration
Potassium
1966-94
Upward
Deterioration
Silica
1966-94
Upward
Deterioration
Sodium
1966-94
Upward
Deterioration
Sulfate
1966-94
Upward
Deterioration
Turbidity
1970-78
Downward
Improvement
Specific conductance
1966-94
Upward
Deterioration
Dissolved Solids
1966-94

1976-94

1987-94

Upward

Upward

Upward

Deterioration

Deterioration

Deterioration

pH
1966-94
Downward
Deterioration
Suspended sediment
1974-94

1987-94

Upward

Downward

Deterioration

Improvement

Total ammonia
1971-94
Downward
Improvement
Total organic carbon
1970-81
Upward
Deterioration
Total phosphorus
1987-94
Downward
Improvement
Barium
1978-94
Downward
Improvement
Iron
1969-94
Downward
Improvement
Fecal coliform
1976-94
Downward
Improvement
Fecal streptococcus
1987-94
Upward
Deterioration
Tamiami Canal Station
Chloride
1967-93
Upward
Deterioration
Fluoride
1967-93
Downward
Improvement
Magnesium
1967-93
Upward
Deterioration
Potassium
1967-93
Upward
Deterioration
Sodium
1967-93
Upward
Deterioration
Specific conductance
1967-93
Upward
Deterioration
Dissolved solids
1967-93
Upward
Deterioration
Dissolved oxygen
1967-93
Downward
Deterioration
Suspended sediment
1976-93
Upward
Deterioration
Total ammonia
1970-92
Downward
Improvement
Total nitrite plus nitrate
1975-85
Downward
Improvement
Barium
1978-93
Downward
Improvement
Strontium
1967-93
Upward
Deterioration


Number of Statistically Significant Trends for Selected Constituents at the Miami and Tamiami Canal Stations Over Time
[MC, Miami Canal station; TC, Tamiami Canal station]
Station
Time period
Number of
upward trends
Number of
downward trends
MC
1966-94
13
8
TC
1966-93
8
5



Click here for a printable version of this poster (note: document will open in a new browser window)

For more information contact:

Clint Lietz
U. S. Geological Survey
(305)717-5838
EMAIL: alietz@usgs.gov

Related information:

SOFIA Project: Determination of Nutrient Loads to East Coast Canals


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U.S. Department of the Interior, U.S. Geological Survey, Center for Coastal Geology
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Last updated: 12 August, 2003 @ 05:11 PM (TJE)