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projects > determination of nutrient loads to east coast canals > abstract


Nutrient Transport to Biscayne Bay and Water-Quality Trends at Selected Sites in South Florida

A. Clint Lietz


Since the 1940's a highly managed water distribution system has been developed in south Florida consisting of levees, pump stations, gated control structures, and water-conservation areas. This complex system was created for the purposes of flood control, water storage, replenishment of ground-water supplies, and retardation of saltwater intrusion. As an unintended consequence, this manmade system has also altered natural hydropatterns and contributed to degraded water quality in south Florida.

Plans for restoring the remaining south Florida ecosystem include development of large surface and subsurface water-storage facilities, filling of canals, removal of levees, and redistribution of water to meet current and future needs of natural and developed areas. Expected results include changes in quantity, timing, and quality of waters delivered to many areas of south Florida. The U.S. Geological Survey, as part of its Place-Based Studies Program, has documented nutrient transport to Biscayne Bay, a shallow subtropical estuary along Florida's southeastern coast, and has analyzed water-quality trends at two long-term sites, one near Biscayne Bay and one within the Big Cypress National Preserve. This information will help provide a baseline and historical perspective against which to evaluate future changes.

Biscayne Bay provides an aquatic environment that is habitat to a diverse population of plant and animal species. As a result of agricultural and urban activities, increased nutrient loads in discharges from the east coast canals are a potential threat to the health of Biscayne Bay (fig. 1). An understanding of past and present nutrient transport to
Map of South FL showing location of study sites, canals, control structures, pumping stations and land-use areas
Figure 1. South Florida showing location of study sites, major canals, control structures, pumping stations, and land-use areas. Click for larger image.
Biscayne Bay is needed to help assess the ecological health of the bay, to help evaluate the water-quality effects if this water is diverted to other areas, and to provide a basis for comparison of future nutrient flow.

Water samples were collected from east coast canals in 1996-97 (primarily during the wet season) to determine concentrations of major organic and inorganic nitrogen and phosphorus species. Study results indicate that within the Biscayne Bay watershed, median concentrations of some nitrogen and phosphorus species were highest in selected land-use categories: (1) nitrite plus nitrate in the agricultural land-use category; (2) ammonia, total phosphorus, and orthophosphate in the urban land-use category; and (3) total organic nitrogen in the wetlands category.

Depth-integrated samples were significantly different in total phosphorus concentration than 25 percent of grab samples at 1.0 meter depth and 33 percent of grab samples collected at 0.5 meter depth. No statistically significant differences were found for total nitrogen between grab and depth-integrated samples. Grab samples also were found to be biased low when compared to depth-integrated samples. A simple linear regression analysis was used to develop models for estimating total nitrogen and total phosphorus loads from the east coast canals to Biscayne Bay. Because of the large number of water samples collected over the years (1987-96) and the availability of continuous discharge record, a log-linear model (ESTIMATOR) employing a minimum variance unbiased estimator, was used to compute total nitrogen and total phosphorus loads for site S-26 in Miami (fig. 1 and table 1).

Restoring and enhancing the natural ecosystem requires an understanding of how water quality has been affected over time by anthropogenic influences in south Florida. Two U.S. Geological Survey daily discharge stations, one located within the wetlands of the Big Cypress National Preserve (Tamiami Canal station) and the other located in an urban area near Biscayne Bay (Miami Canal station), were analyzed for long- term (1966-94) trends in water quality to characterize pre-restoration water quality in different land-use categories and to document changes in water quality over time.

The principal tool used for the water-quality analysis was the Seasonal Kendall Trend (SKT) test, a nonparametric test that compares relative ranks of data values from the same seasons to negate variation caused by seasonality. To discern the anthropogenic influences that have affected water quality over the years, variation caused by discharge also should be negated. This was accomplished by performing the SKT test on flow-adjusted concentrations (residuals) from statistically significant concentration/discharge relations developed using linear regression models. Long-term trends were determined at both sites for selected major inorganic constituents and physical characteristics; pH and dissolved oxygen; suspended sediment; nitrogen, phosphorus, and carbon species; trace metals; and bacteriological and biological characteristics.

Statistically significant (p-value less than 0.01) temporal trends for water-quality constituents at the Miami and Tamiami Canal stations were classified as indicators of either improvement or deterioration in water quality over time (table 2). Most downward trends indicate improvement in water quality over time; however, downward trends in pH and dissolved oxygen indicate deterioration over time and the potential for harmful effects on aquatic life. At the Miami Canal station, improvement in water quality was documented by 7 trends and deterioration in water quality was documented by 14 trends. At the Tamiami Canal station, improvement and deterioration in water quality were indicated by 4 and 9 trends, respectively. Median and maximum concentrations at both sites were compared to the State of Florida freshwater standards; most concentrations were within these standards. However, the median concentrations of dissolved oxygen at the Miami and Tamiami Canal stations were 3.3 and 2.7 milligrams per liter, respectively, and did not meet the State fresh-water standard of at least 5.0 milligrams per liter. Additionally, the median and maximum concentrations of total ammonia at both sites exceeded the State freshwater standard of 0.02 milligram per liter.

Table 1. Summary statistics for the estimation of total nitrogen and total phosphorus loads at site S-26 computed by the ESTIMATOR program for water years 1987-96.
Water year Constituent Maximum monthly mean daily load
(tons per day)
Minimum monthly mean daily load
(tons per day)
Annual daily load
(tons per year)
1987 Total nitrogen
Total phosphorus
0.72
.008
0.011
1.85 x 10
-4
78.2
.70
1988 Total nitrogen
Total phosphorus
1.68
.021
.004
6.32 x 10
-4
190
2.47
1989 Total nitrogen
Total phosphorus
.54
.007
.00
.00
46.5
.61
1990 Total nitrogen
Total phosphorus
1.01
.012
.00
.00
85.5
1.11
1991 Total nitrogen
Total phosphorus
1.60
.018
.013
2.21 x 10
-4
144
1.81
1992 Total nitrogen
Total phosphorus
2.63
.028
.040
6.55 x 10
-4
261
2.98
1993 Total nitrogen
Total phosphorus
1.04
.012
.008
1.38 x 10
-4
188
2.18
1994 Total nitrogen
Total phosphorus
.77
.008
.018
2.48 x 10
-4
127
1.45
1995 Total nitrogen
Total phosphorus
2.00
.019
.00
.00
268
2.71
1996 Total nitrogen
Total phosphorus
1.72
.016
.00
.00
199
2.19

Table 2. Summary of water-quality indicators showing improvement or deterioration at the Miami and Tamiami Canal stations over time

[Based on trends determined at a p-value of 0.10]

Water-quality constituent Time period Trend Effect on water quality
Miami Canal Station
Chloride 1966-94 Upward Deterioration
Magnesium 1966-94 Upward Deterioration
Potassium 1966-94 Upward Deterioration
Silica 1966-94 Upward Deterioration
Sodium 1966-94 Upward Deterioration
Sulfate 1966-94 Upward Deterioration
Turbidity 1970-78 Downward Improvement
Specific conductance 1966-94
1966-94
Upward
Upward
Deterioration
Deterioration
Dissolved Solids 1976-94
1987-94
Upward
Upward
Deterioration
Deterioration
pH 1966-94 Downward Deterioration
Suspended sediment 1974-94
1987-94
Upward
Downward
Deterioration
Improvement
Total ammonia 1971-94 Downward Improvement
Total organic carbon 1970-81 Upward Deterioration
Total phosphorus 1987-94 Downward Improvement
Barium 1978-94 Downward Improvement
Iron 1969-94 Downward Improvement
Fecal coliform 1976-94 Downward Improvement
Fecal streptococcus 1987-94 Upward Deterioration
Tamiami Canal Station
Chloride 1967-93 Upward Deterioration
Fluoride 1967-93 Downward Improvement
Magnesium 1967-93 Upward Deterioration
Potassium 1967-93 Upward Deterioration
Sodium 1967-93 Upward Deterioration
Specific conductance 1967-93 Upward Deterioration
Dissolved solids 1967-93 Upward Deterioration
Dissolved oxygen 1967-93 Downward Deterioration
Suspended sediment 1976-93 Upward Deterioration
Total ammonia 1970-92 Downward Improvement
Total nitrite plus nitrate 1975-85 Downward Improvement
Barium 1978-93 Downward Improvement
Strontium 1967-93 Upward Deterioration


(This abstract was taken from the Greater Everglades Ecosystem Restoration (GEER) Open File Report (PDF, 8.7 MB))

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