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Ground Water and Ecosystems Restoration Research
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GWERD Research on NAPL Source Zones

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The remediation of subsurface formations contaminated by non-aqueous phase liquids (NAPLs) is a major impediment to the restoration of many hazardous waste sites. NAPLs are classified as those lighter than water (LNAPL) or denser than water (DNAPL) and can serve as long-term sources of contamination impacting both ground water and surface water. Conventional remediation techniques designed for dissolved contaminant removal have proven inadequate for achieving acceptable environmental cleanup goals within reasonable time frames for NAPL-contaminated source zones.

Field-scale research has demonstrated that a high percentage of NAPL mass can be rapidly depleted within source zones by using aggressive in-situ thermal or chemical flushing technologies. Even with these aggressive technologies, the efficiency of NAPL depletion often decays exponentially with increasing mass removed and complete NAPL removal may not be technically or economically feasible. For such sites, the key questions are: 1) how much NAPL must be removed to be protective of human health and the environment, and 2) are current technologies adequate to achieve this level of removal. To answer these questions, we must understand the relationships between NAPL mass depletion, contaminant mass flux from the source zone, and dissolved plume properties.

GWERD research is focused on three critical aspects:

  • Demonstration, evaluation, and optimization of NAPL remediation technologies
  • Assessment and prediction of the benefits of partial NAPL depletion
  • Development and assessment of integrated NAPL source remediation approaches

GWERD conducts applied and fundamental research to further develop source zone remediation technologies and to understand the relationship between source zone mass removal and risk reduction.

 

Projects

Publications

  • Mravik, S.C., R.K. Sillan, A.L. Wood and G.W. Sewell. 2003. Field Evaluation of the solvent extraction residual biotreatment technology. Environ. Sci. Technol. 37: 5040-5049.
  • Jeong, S.-W., A.L. Wood and T.R. Lee. 2003. Enhanced removal of DNAPL trapped in porous medial using simultaneous injection of cosolvent with air: influencing factors and removal mechanisms. J. Hazardous Materials B101: 109-122.
  • Huling, S.G., R.G. Arnold and R.A. Sierka. 2001. Influence of Peat on Fenton Oxidation. Water Research 35 (7): 1687-1694.

 

 

 
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