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EPA 540/F-93/502

Electron Beam Treatment for the Removal of Benzene
and Toluene from Aqueous Streams and Sludge
Florida International University and the University of Miami

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Electron Beam Treatment for the Removal of Benzene and Toluene from Aqueous Streams and Sludge Florida International University and the University of Miami (16K)


ABSTRACT

Electron Beam Treatment for the Removal of Benzene and Toluene from Aqueous Streams and Sludge
Florida International University and the University of Miami Emerging Technology Bulletin
EPA 540/F-93/502
April 1993

The electron accelerator utilized in this treatment process has a potential of 1.5 MeV, rated from 0 to 50 mA, providing radiation doses of 0-850 krad (0-8.5 kGy). The reactive transients initiate thousands of chemical reactions capable of destroying hazardous compounds in aqueous solution, in most cases, mineralizing them to carbon dioxide, water, and salt. The process is essentially pH independent in the range 3-11. No residual sludge is formed and no pretreatment is necessary. The reaction by-products are formed at relatively low concentration and are non-toxic. This process has demonstrated the ability to treat complex mixtures of hazardous chemicals in drinking water, groundwater, wastewater, sludge, and water containing up to 5 percent suspended solids. It has been shown to be effective in removing numerous organic contaminants. The removal of benzene and toluene from aqueous solution has been evaluated as a function of solute concentration, absorbed dose, pH, and total solids content. For both benzene and toluene, the sum of the reaction by-products identified, as well as any unreacted solute, accounted for less than 9 percent of the total carbon mass balance for benzene and less than 2 percent of the total carbon mass balance for toluene at an absorbed dose of 200 krad.

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Posted February 26, 1999

 

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