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Photoelectrocatalytic Degradation and Removal
of Organic and Inorganic Contaminants in Ground Waters

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Photoelectrocatalytic Degradation and Removal
of Organic and Inorganic Contaminants in Ground Waters
EPA 540/F-01/502
April 2001

Abstract:

Technology Description: The University of Wisconsin – Madison (UW-Madison) is developing a photocatalytic technology that uses titanium dioxide (TiO2) suspensions to coat various supports used in aqueous treatment applications. Photocatalysis involves the use of UV light to illuminate the surface of a catalyst such as TiO2. As the photocatalyst absorbs near- UV light, electrons in the valence band are excited into the conduction band and produce highly reactive electrons and holes that promote oxidation of organic compounds. In this project researchers sought to overcome some of the challenges of photocatalysis by developing a “biased” photoreactor. A metallic substrate was coated with TiO to prepare a 2 photoelectrode which was then combined with a cathode to form an electrolytic cell. UV light illuminates the TiO2 coating on the electrode and allows the electrolytic cell to serve as a biased photoreactor, which was the subject of this study. A design for a biased photoreactor in an annular configuration is shown below. A similar system was employed for this project.

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Posted February 07, 2002

 

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