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Contaminated sediments news

Issue 39 - July 2003

Welcome to the Contaminated Sediments News, a monthly review of recent journal articles, issues in the press, upcoming conferences, and other news.  Items for the CS News are chosen from the results of a detailed search of a number of scientific and technical publication databases, as well as from searches of media publication databases (including newspapers and magazines).

Check back to this site frequently to see each new issue of the Contaminated Sediments News, and visit the CS News Archive to find past issues.

Contents

Note: The summaries found on this website are based on articles from the press and from peer-reviewed publications, and they represent the opinions of the original authors. The views of authors expressed herein do not necessarily state or reflect those of the United States Government, and shall not be used for advertising or product endorsement purposes. Reference herein to any specific commercial products, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government.

Summarized Journal Articles

  • In situ bioassay chambers and procedures for assessment of sediment toxicity with Chironomus riparuis The authors developed a sediment bioassay chamber to use in performing in situ toxicity bioassays using the midge Chironomus riparius, a benthic invertebrate. This paper also describes experimental protocol for using the newly designed test chamber. Tests were done to evaluate a comparison of the responses of C. riparius to the in situ conditions of the bioassay chamber to those obtained under controlled conditions, which consisted of laboratory 10-day larval growth and survival tests. The in situ test procedures call for clean sand, local sediment, and formulated sediment to be incorporated in the in situ bioassay, which is intended to minimizing natural variability. Some of the natural variation may be due to physicochemical differences among sediments or interactions with indigenous organisms. Analysis of the results show that recovery of C. riparius generally ranged from 80-100% in the control and reference site. These levels of recovery are good and indicate that the new chamber and protocol were suitable for exposing and retrieving C. riparius in situ. Results also showed differences between responses obtained with formulated and natural sediment in situ, as well as between laboratory and in situ.

    Source: Castro, B.B. et al.; In situ bioassay chambers and procedures for assessment of sediment toxicity with Chironomus riparuis; Environmental Pollution 125 (3): 325-335, 2003.

  • Stimulated embryo production as a parameter of estrogenic exposure via sediments in the freshwater mudsnail Potamopyrgus antipodarum – This study evaluated the use of a whole-sediment biotest with the freshwater mudsnail Potamopyrgus antipodarum (Gastropoda, Prosobranchia) for determining potential effects of three suspected endocrine disrupting chemicals. The xeno-estrogens bisphenol A (BPA), 4-tert-octylphenol (OP) and 4-n-nonylphenol (NP), were investigated. Artificial sediments were spiked with five nominal concentrations of BPA or OP, ranging from 1-300 µg/kg dry weight For NP, six nominal concentrations (1-1000 µg/kg for NP) were used to spike the artificial sediments. Response of the P. antipodarum after 2, 4 and 8 weeks exposure were analyzed. The authors found the response of P. antipodarum to increased exposure times and/or concentrations of BPA and OP (compared to a solvent spiked control sediment) was that the organisms exhibited a distinct increase in the number of embryos sheltered in its brood pouch. The most sensitive response parameter was the number of new, still unshelled embryos. The lowest observed effect concentration (LOEC) for BPA and OP was shown to be the lowest administered concentration (1 µg/kg) for most response parameters after 8 weeks of exposure.

    Calculated effect concentrations for BPA (unshelled embryos after 2 weeks exposure):
    • EC10 0.22 µg BPA/kg
    • EC50 24.5 µg BPA/kg

      Calculated effect concentrations for BPA (unshelled embryos after 4 weeks exposure):
    • EC10 0.19 µg BPA/kg
    • EC50 5.67 µg BPA/kg

      Calculated effect concentrations for OP (unshelled embryos after 4 weeks):
    • EC10 4 ng OP/kg
    • EC50 0.07 µg OP/kg

For NP, there was no clear concentration-dependent response, so no EC10 or EC50 could be estimated. The LOEC in the experiments with NP was 10 µg g/kg. The authors concluded that their research indicates P. antipodarum is highly sensitive to the tested endocrine disruptors at environmentally relevant concentrations. Additionally, they noted that the biotest with P. antipodarum is a useful tool for the identification of sediment-bound pollutants and for the assessment of sediment quality.

Source: Duft, M. et al.; Stimulated embryo production as a parameter of estrogenic exposure via sediments in the freshwater mudsnail Potamopyrgus antipodarum; Aquatic Toxicology 64 (4): 437-449, 2003.

  • Degradation of nonylphenol ethoxylates in estuarine sediment under aerobic and anaerobic conditions – Nonylphenol ethoxylate (NPEO) surfactants and their metabolites are ubiquitous aquatic contaminants, which have been extensively studied to determine their environmental fate related to concerns about toxicity and estrogenic activity. However, the pathways of NPEO degradation in sediments, which appears to be an important sink for these compounds in the environment, have not previously been reported in the scientific literature. The authors examined the rates and pathways of NPEO degradation in batch sediment slurry experiments using radiolabeled NPEO mixtures and found that NPEOs are more persistent in sediments under anaerobic conditions than in the presence of oxygen. NPEO degradation was found to proceed via separate pathways in oxic and anoxic sediment. As a part of the study, the authors were able to identify discernible metabolites and estimate an overall mass balance for NPEO degradation in oxic and anoxic sediment. In contrast with previous studies, no evidence was observed for net production of nonylphenol from NPEOs during aerobic or anaerobic degradation. The authors observed that the relative degradation rates of NPEO ethoxymers in sediment slurry experiments to be consistent with previous reports for these compounds in sediment and other environmental media. However, the absolute degradation rates measured in this study were somewhat faster than those reported for field sediments.

    Source: Ferguson, P.L. and B.J. Brownawell; Degradation of nonylphenol ethoxylates in estuarine sediment under aerobic and anaerobic conditions; Environmental Toxicology and Chemistry/SETAC 22 (6): 1189-1199, 2003.

  • PCB and PAH speciation among particle types in contaminated harbor sediments and effects on PAH bioavailability – This research evaluated the distribution of PCB and PAH at a particle-scale in sediments obtained from three urban locations in the United States: Hunters Point, CA; Milwaukee Harbor, WI; and Harbor Point, NY. The sediments from these locations were composed of mineral grains (primarily sand, silt, and clays) and carbonaceous particles (primarily coal, coke, charcoal, pitch, cenospheres, and wood). Density separation techniques were used to separate the carbonaceous sediment fractions from the mineral fractions. The carbonaceous fractions were then identified by petrographic analysis. In all three sediments, carbonaceous particles contributed 5-7% of the total mass and 60-90% of the PCBs and PAHs. The authors note that the production of carbonaceous particles is not typically associated with PCB contamination, which makes it very unlikely that these particles can be the source of PCBs in the environment. They note that the carbonaceous particles act as sorbents to preferentially accumulate PCBs in the aqueous environment. The assumed sources of the PCBs are direct releases to the sediment or air deposition as soot particles.

    Treatment of the sediment in an aerobic bioslurry resulted in negligible PAH loss from the carbonaceous coal-derived material in Milwaukee Harbor. However, the same treatment resulted in 80% of the PAHs being removed from carbonaceous particles in Harbor Point sediment. Microscale PAH extraction and analysis revealed that PAHs in Harbor Point sediment were associated mainly with coal tar pitch residue. PAHs present in semisolid coal tar pitch are more bioavailable than PAHs sorbed on carbonaceous particles such as coal, coke, charcoal, and cenosphere. Results of this study illustrate the importance of understanding characteristics of the sediment, i.e., particle-scale association, of hydrophobic organic contaminants for explaining bioavailability differences among sediments.

    Source: Ghosh, U. et al.; PCB and PAH speciation among particle types in contaminated harbor sediments and effects on PAH bioavailability; Environmental Science & Technology 37 (10): 2209-2217, 2003.

  • Uptake and depuration of 4-nonylphenol by the benthic invertebrate Gammarus pulex: how important is feeding rate? – The water column is generally thought to be the major exposure and uptake route for soluble toxins by aquatic organisms. However, for hydrophobic chemicals (like many organic chemicals), exposure and uptake through diet are often the more important exposure pathways because these types of chemicals adsorb onto organic sediments and food. 4-nonylphenol (NP) has recently become more closely scrutinized because of its toxicity and possible endocrine disrupting effects in aquatic life. NP is a persistent and hydrophobic (log KOW = 4.48) contaminant in many aquatic systems, including water column and sediments. In this study, the relative importance of NP uptake through accumulation from diet and water was examined for the detritus-feeding freshwater shrimp Gammarus pulex. The authors used a bootstrap nonlinear regression technique, to estimate the level of NP present in G. pulex at any time during or after initial exposure. Heterogeneity, together with assumptions on feeding rate, was shown to significantly affect the determination of NP uptake. The results of the study suggest that major uptake of NP by G. pulex may be through food and sediment, but may also occur through water column exposure. The statistical and modeling methodology developed for this study may be applied to other uptake and depuration assessments for any aquatic organisms exhibiting a variable feeding phase.

    Source: Gross-Sorokin, M.Y. et al.; Uptake and depuration of 4-nonylphenol by the benthic invertebrate Gammarus pulex: how important is feeding rate?; Environmental Science & Technology 37 (10): 2236-2241, 2003.

  • Altered swimming performance of a benthic fish (Erimyzon sucetta) exposed to contaminated sediments – Coal combustion wastes (ash) have been shown to adversely affect fish populations, but few controlled laboratory studies have evaluated the responses of individual fish to ash exposure. Available information in the literature suggests that sublethal effects (i.e., decreased growth rates and reduced fecundity) of ash may be important causes of toxicity. In this study, the authors hypothesized that ash may have other important effects on fish, such as altering swimming performance. To test this hypothesis, the authors measured sprint speed and critical swimming speed of juvenile lake chubsuckers (Erimyzon sucetta) exposed to ash in the laboratory. Fish exposed to ash for 90-100 days showed the following effects:

    • Accumulation of significant concentrations of As, Se, Sr, and V
    • Exhibiting severe fin erosion
    • Reduced sprint speed and maximum swimming speed

Compared to controls, sprint speed of ash-exposed fish was reduced by 30% at 5 cm and the percent reduction was further reduced to 104% at 20 cm. Critical swimming speed was approximately 50% lower in fish exposed to ash compared to controls. Additionally, the typical positive relationship between standard length and critical swimming speed was absent in fish exposed to ash. Reductions in swimming performance could not be attributed to pollutant-induced differences in body condition or fin morphology. The authors concluded that physiological disruptions (e.g., increased energy demands, decreased oxygen uptake or transport) are responsible for the observed effects and warrant further attention.

Source: Hopkins, W.A. et al.; Altered swimming performance of a benthic fish (Erimyzon sucetta) exposed to contaminated sediments; Archives of Environmental Contamination and Toxicology 44 (3): 383-389, 2003.

  • Biological effects of marine PCB contamination on black guillemot nestlings at Saglek, Labrador: liver biomarkers – Marine sediment contamination around a former military site are linked to elevated polychlorinated biphenyl (PCB) concentrations in black guillemots (Cepphus grylle) in Saglek Bay, Labrador. The authors measured liver biomarkers and sigma PCB concentrations in 31 nestlings from three PCB-exposure groups:

    • Reference group (range: 15-46 ng/g liver, wet wt.)
    • Moderately exposed Islands group (24-150 ng/g)
    • Highly exposed Beach group (170-6200 ng/g)

    Biomarker responses were found to be dose-dependent and in some cases sex-dependent. Livers of female Beach nestlings were 36% larger than Reference females. In both sexes, Beach nestlings had 79% greater liver ethoxyresorufin-O-deethylase (EROD) activities and 47% lower liver retinol concentrations. Retinyl palmitate concentrations were 50% lower among female nestlings. Island nestlings showed similar responses, including 57% increase in EROD, 28% reductions in retinol and 58% reduction in retinyl palmitate concentrations. Liver lipid content increased with sigmaPCBs in both sexes, and correlated with liver mass in males. Malic enzyme activity and porphyrin concentrations showed little association with sigmaPCBs. Although similar associations between liver biomarkers and organochlorine exposure in fish-eating birds are well documented, typically exposures involve multiple contaminants and there is uncertainty about specific PCB effects. Results from this study indicate that liver biomarkers respond to relatively low PCB exposures (approximately 73 ng/g liver) in guillemots.

    Source: Kuzyk, Z.Z.A. et al.; Biological effects of marine PCB contamination on black guillemot nestlings at Saglek, Labrador: liver biomarkers; Ecotoxicology 12 (1-4): 183-197, 2003.

  • Analysis of pesticides in water and sediment under different storage conditions using gas chromatography – This paper describes the testing a simple low-solvent method for simultaneously extracting five classes of pesticides (triazines, organophosphates, organochlorines, pyrethroids, and carbamates) from reconstituted water and sediment. The method uses common techniques, including solid phase extraction (SPE) and sonication in combination with gas chromatography. The authors found pesticide recoveries ranged from 60 to 120%. However, carbaryl, dicofol, and methoxychlor had higher recoveries. Pond water and soil were used to further test the method. The recoveries of pesticides from soil were comparable with those from sediments. Pond water recoveries of the organochlorines exceeded 100%. A matrix enhancement effect was suspected to be the cause for the observed elevated recoveries. The authors also evaluated storage time to determine time range and conditions in which the samples can be stored without significant losses. Recoveries of pesticides in water and sediment were monitored for 28 days. Water samples were most stable when extracted immediately and stored in SPEs in the freezer. These samples remained stable for up to six weeks in the freezer. Sediment samples were stored for a month without a significant decrease in pesticide concentrations.

    Source: Lyytikainen, M. et al.; Analysis of pesticides in water and sediment under different strorage conditions using gas chromatography; Archives of Environmental Contamination and Toxicology 44 (4): 437-444, 2003.

  • A simplified approach for monitoring hydrophobic organic contaminants associated with suspended sediment: methodology and applications – Hydrophobic organic contaminants, are frequently detected in bed sediment and in aquatic biota, but rarely detected in whole-water samples. This complicates determination of their occurrence, load, and source. The direct analysis of sediment in suspension would be a better approach for measuring the effects of hydrophobic organic contaminants. However, procedures for direct measurement are expensive and cumbersome. The authors describe a simple, inexpensive methodology for dewatering sediment. Inline filtration of large volumes of water allows the isolation of a sufficient mass of sediment for analyses of organochlorine compounds and PAHs. The sediment is removed from the filters and analyzed directly by standard laboratory methods. In the first case study, suspended-sediment sampling was used to determine occurrence, loads, and yields of contaminants in urban runoff affecting biota in Town Lake, Austin, TX. The second case study used suspended-sediment sampling to locate a point source of PCBs in the Donna Canal in south Texas, where fish are contaminated with PCBs. The case studies demonstrate that suspended-sediment sampling can be an effective tool for determining the occurrence, load, and source of hydrophobic organic contaminants in transport.

    Source: Mahler, B.J., and P.C. Van Metre; A simplified approach for monitoring hydrophobic organic contaminants associated with suspended sediment: methodology and applications; Archives of Environmental Contamination and Toxicology 44 (3): 288-297, 2003.

  • In situ microcosms to study the impact of heavy metals resuspended by dredging on periphyton in a tropical estuary – Reclamation, dredging, construction and shipping heavily impact Ponggol estuary, located on the northeastern coast of Singapore. Tin, lead, nickel, cadmium, copper and zinc in the particulate and dissolved fraction and in sediments were monitored biweekly in the estuary from July 1999 to June 2000. The results show observed dissolved, particulate and sediments fraction concentration ranges of

    • Tin non detect (ND)-92 ppm
    • Lead ND-303 ppm
    • Nickel ND-2818 ppm
    • Cadmium ND-74 ppm
    • Copper ND-1117 ppm
    • Zinc ND-137000 ppm

    The authors noted intensive dredging activity occurred during the monitoring period that may have led to the resuspension and increased bioavailability of particulate metals. Periphytic algae were established on glass slides and exposed to previously measured environmental levels of heavy metals using in situ estuarine microcosms. The toxicity of heavy metals in various fractions to periphytic algae was assessed from the changes in their chlorophyll a content. Cadmium had the least significant effect followed by lead, zinc, nickel, tin and copper at all concentrations tested. A reduction in periphyton biomass (with respect to controls) of 95-100% was observed for treatments with metals in particulate form. In addition, exposure to contaminated sediments for 3 days significantly decreased chlorophyll a by 90-99% compared to controls. The authors suggest that high concentrations of zinc (9893-17240 mg/L), copper (5-11 mg/L) and cadmium (1-1.8 mg/L) recorded in the aqueous phase of treatment microcosms, and attributed to release from the contaminated sediments, could account for the toxicity to periphyton.

    Source: Nayar, S. et al.; In situ microcosms to study the impact of heavy metals resuspended by dredging on periphyton in a tropical estuary; Aqautic Toxicology 64 (3): 293-306, 2003.

  • Delayed gametogenesis and progesterone levels in soft-shell clams (Mya arenaria) in relation to in situ contamination to organotins and heavy metals in the St. Lawrence River (Canada) – There is a growing awareness that endocrine disrupting contaminants in the aquatic environment may alter steroid hormone levels and affect the reproductive success of the invertebrates. This study attempted to determine the effect of heavy metals and organotins on sexual maturation in Mya arenaria. Individuals were collected from July to November 1998, at different sites along the South coast of the St. Lawrence maritime estuary. Near the Rimouski harbor, clams showed high levels of tributyltin (TBT), and dibutyltin (DBT) in the gonad, along with a lower gonado-somatic index {GSI=gonad wet weight (g)/body wet weight without shell (g) x 100}, low progesterone levels and a delay in sexual maturation when compared to the reference site. Sites that had intermediate levels of contaminants exhibited intermediate responses of hormones and sexual maturation stages. The authors suggested that TBT and DBT are endocrine disruptors in clams. Further studies will however be necessary to investigate in more details how contaminants such as TBT can affect the steroid hormones production in the gonads of M. arenaria.

    Source: Siah, A. et al.; Delayed gametogenesis and progesterone levels in soft-shell clams (Mya arenaria) in relation to in situ contamination to organotins and heavy metals in the St. Lawrence River (Canada); Comparative Biochemistry and Physiology Part C: Toxicology & Pharmacology 135 (2): 145-156, 2003.

  • Direct determination of polycyclic aromatic hydrocarbons in solid matrices using laser desorption/laser photoionization ion trap mass spectrometry – This study evaluated the development and characterization of a new instrument for solid sampling which couples IR laser desorption followed by UV laser photo-ionization and analysis using an ion trap mass spectrometer. The method was calibrated with a new type of solid sample preparation involving activated charcoal as the solid substrate. This solid sample provided a steady signal for several thousand-laser shots, which allowed optimization of the experimental procedure. The authors found that the IR and UV intensity and the delay between them are important components of the observed magnitude and type of signals. A method of gas phase accumulation with multiple laser shots was examined. Finally, this technique was demonstrated to be effective in providing direct qualitative information for N.I.S.T. SRM 1944 river sediment sample with no sample pre-treatment.

    Source: Specht, A.A., and M.W. Blades; Direct determination of polycyclic aromatic hydrocarbons in solid matrices using laser desorption/laser phontoionization ion trap mass spectrometry; Journal of the American Society for Mass Spectrometry 14 (6): 562-570, 2003.

  • Histopathologic and histochemical biomarker responses of Baltic clam, Macoma balthica, to contaminated Sydney Harbor sediment, Nova Scotia, Canada – Sediments in Sydney Harbour, Nova Scotia, are highly contaminated by PAHs, PCBs, and heavy metals. The Baltic clam, Macoma balthica, was used as a test organism and exposed to 11 Sydney Harbour sediment samples. Histopathologic and histochemical evaluations were made. Histologic lesions in digestive gland (tubular dilation or atrophy, macrophage aggregates, tubular cell necrosis, and tissue inflammation) and gonads (macrophage aggregates, supporting cell, germ cell, and ovarian cell necroses) were frequently detected in clams exposed to the most contaminated sediments from the harbor. Clams exposed to these contaminated sediments also had the highest acid phosphatase activity. The average scores of tubular dilation or atrophy, ovarian cell necrosis, and the sums of mean digestive gland lesions correlated significantly with sediment PCBs, and the activities of acid phosphatase correlated significantly with sediment heavy metals, PAHs, and PCBs. Among the lesions, digestive gland tubular dilation or atrophy, tubular cell, germ cell, and ovarian cell necroses, and the activity of acid phosphatase are the best sublethal effect indicators in Macoma exposed to Sydney Harbour sediments.

    Source: Tay, K.L. et al.; Histopathologic and histochemical biomarker responses of Baltic clam, Macoma balthica, to contaminated Sydney Harbor sediment, Nova Scotia, Canada; Environmental Health Perspectives 111 (3): 273-280, 2003.

  • Microbial mercury transformation in anoxic freshwater sediments under iron-reducing and other electron-accepting conditions – Different terminal electron-accepting processes (TEAPs) were used to determine potential rates of microbial methylation of inorganic mercury (added as HgCl2) and degradation of methyl mercury (MeHg) (added as CH3HgCl). The authors investigated methylation and degradation of mercury in anoxic sediments from the Mobile Alabama River Basin (MARB). The authors used the following TEAPs:

    • methanogenic conditions
    • sulfate-reducing conditions
    • iron-reducing conditions

    Potential rates of methylation were comparable under methanogenic and sulfate-reducing conditions but suppressed under iron-reducing conditions, in slurries of freshwater wetland sediment. In contrast, MeHg degradation rates were similar under all three TEAPs. Microbial Hg methylation and MeHg degradation were also investigated in surface sediment from three riverine sites, two of which had iron reduction and one sulfate reduction, as the dominant TEAP. Methylation was active in sulfate-reducing sediments of a tributary creek and suppressed in iron-reducing, sandy sediments from the open river, whereas MeHg degradation was active at all three sites. Although iron-reducing conditions often suppressed methylation, some methylation activity was observed in two out of three replicates from iron-reducing sediments collected near a dam. Given that MeHg degradation was consistently observed under all TEAPs, the authors suggest that the net flux of MeHg from iron-reducing surface sediments may be suppressed (due to inhibition of gross MeHg production) compared to sediments supporting other TEAPs.

    Source: Warner, K.A. et al.; Microbial mercury transformation in anoxic freshwater sediments under iron-reducing and other electron-accepting conditions; Environmental Science & Technology 37 (10): 2159-2165, 2003.

  • Effects of sampling, preparation, and defecation on metal concentrations in selected invertebrates at urban sites This study attempted to obtain basic information for designing standardized test preparation methods. Heavy metals Zn, Cu, Cd and Pb were measured in gastropods (Xerolenta obvia), oligochaetes (Lumbricus terrestris), isopods (Armadillidium vulgare, Trachelipus rathkei) and carabids (Harpalus rubripes, Calathus fuscipes) using different sampling methods and different modes of sample treatment.

    • Higher Zn, Cd and Pb, and lower Cu-contents were observed in isopods and carabids trapped with formalin-pitfalls compared to manually collected specimens (which were allowed to defecate).
    • Defecation had marked effects on the levels of all four metals investigated in oligochaetes, and on Cd and Pb in gastropods and isopods.
    • Cellulose was fed as an accelerator of gut passage and showed a significant effect on the Pb concentration in the soft body of gastropods.
    • Deionate-washed isopods (A. vulgare) showed higher Cd concentrations than ultrasonic-cleaned individuals.
    • No marked differences were observed between heat-dried and freeze-dried isopods.
    • Carabids showed strong sex-specific differences in metal concentrations.


    Based on these and previous results, the authors suggest that invertebrates should be:

    • Collected in vivo
    • Allowed to defecate
    • Freeze-fixed
    • Ultrasonic-cleaned (at least in arthropods)
    • Determined to species level and in certain groups (carabids) also to sex
    • Sized or sorted by size (age) before further preparation and analysis.

    If any of these treatments is impractical, comparable sampling and preparation methods are recommended as a minimum requirement in order to avoid bias in the results and/or interpretation.

Source: Zodl, B., and K.J. Wittmann; Effects of sampling, preparation, and defecation on metal concentrations in selected invertebrates at urban sites; Chemosphere 52 (7): 1095-1103, 2003.

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Other Journal Titles of Interest

  • Temporal and spatial distributions of contaminants in sediments of Santa Monica Bay, California. Bay, S. M., E.Y. Zeng, T.D. Lorenson, K. Tran, and C. Alexander. Marine Environmental Research 56 (1-2): 255-276, 2003.

  • Sedimentary nonylphenol contamination in an urbanized, industrialized segment of the Delaware River estaury, USA. Ashley, J.T.F., A. Moore, H.M. Stapleton, D.J. Velinsky, and M.P. Wilhelm. Bulletin of Environmental Contamination and Toxicology 70 (5): 978-984, 2003.

  • Modified clean-up for PBDD, PBDF, and PBDE with an active carbon column--its application to sediments. Choi, J.W., J. Onodera, K. Kitamura, S. Hashimoto, H. Ito, N. Suzuki, S. Sakai, and M. Morita. Chemosphere, In Press, Available online 20 June, 2003.

  • Toxicity assessment of sediement cores from Santa Monica Bay, California. Greenstein, D., S. Bay, A. Jirik, J. Brown, and C. Alexander. Marine Environmental Research 56 (1-2): 277-297, 2003.

  • Examination of hydrophobic contaminant adsorption in mineral micropores with grand canonical Monte Carlo simulations. Luo, J., and J. Farrell. Environmental Science & Technology 37 (9): 1775-1782, 2003.

  • In situ anaerobic degradation of petroleum alkanes in marine sediments: preliminary results. Massias, D., V. Grossi, and J.C. Bertrand. Comptes Rendus Geosciences 335 (5): 435-439, 2003.

  • Effects of zinc and cadmium on the borrowing behavior, LC(50), and LT(50) on Donax trunculus Linnaeus (Bivalvia-Donacidae). Neuberger-Cywiak, L., Y. Achituv, and E.M. Garcia. Bulletin of Environmental Contamination and Toxicology 70 (4): 713-722, 2003.

  • Reductive dechlorination of polychlorinated biphenyls in sediment from the Twelve Mile Creek arm of Lake Hartwell, South Carolina, USA. Pakdeesusuk, U., D.L. Freedman, C.M. Lee, and J.T. Coates. Environmental Toxicology and Chemistry/SETAC 22 (6): 1214-1220, 2003.

  • Dehalogenation of 2,6-dibromobiphenyl and 2,3,4,5,6-pentachlorobiphenyl in contaminated estaurine sediment. Palekar, L.D., K.A. Maruya, J.E. Kostka, and J. Wiegel. Chemosphere, In Press, Available online 16 June, 2003.

  • Sediment toxicity in Central and South Florida ecosystems. Rand, G.M., J.F. Carriger, T.A. Lee, R.J. Pfeuffer, and L.E. Fink. Bulletin of Environmental Contamination and Toxicology 70 (3): 494-501, 2003.

  • Assessment of a sequential extraction procedure for perturbed lead-contaminated samples with and without phosphorus amendments. Scheckel, K.G., C.A. Impellitteri, J.A. Ryan, and T. McEvoy. Environmental Science & Technology 37 (9): 1892-1898, 2003.

  • Influence of desorption and contact time on sediment-water distribution of spiked polychlorinated biphenyls and polycyclic aromatic hydrocarbons: relation with in situ distribution. ten Hulscher, T., B. Vrind, H. van den Heuvel, P. van Noort, and H. Govers. Environmental Toxicology and Chemistry/SETAC 22 (6): 1208-1213, 2003.

  • Comparing methods and sediment contaminant indicators for determining produced water fate in a Louisiana estuary. Woodall, D.W., N.N. Rabalais, R.P. Gambrell, and R.D. DeLaune. Marine Pollution Bulletin 46 (6): 731-740, 2003.

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Upcoming Events and Conferences

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  • DIOXIN2003. The 23rd International Symposium on Halogenated Environmental Organic Pollutants and POPs in Boston, Massachusetts will be held August 24-29. Topics addressed at this conference will include assessment and monitoring of persistent organic pollutants, effects on human health, and environmental policy related to contaminated sediments. For more information, visit www.dioxin2003.org/index1.htm or contact Laura Biringer Michael P. Wasserman, Inc. 349 Newbury Street #300, Boston, MA 02115. Phone 617-262-3424; fax 617-262-3387; e-mail Lbiringer@mpwi.org.

  • Coastal Structures Conference, Portland, Oregon. A Coastal Structures Conference will take place August 26-29 at Embassy Suites, Portland, Oregon. Topics to be addressed will include: functional and structural design; rubble mound breakwaters, revetments, jetties; shore protection structures; caisson breakwaters; innovative structures; wave-structure interaction; physical modeling; geotechnical design and performance; and many other subjects, including dredge disposal caps/environmental containment. For more information, contact the American Society of Civil Engineers, World Headquarters, 1801 Alexander Bell Drive Reston, Virginia 20191-4400. Phone: 800-548-2723 or 703-295-6300, or visit http://www.asce.org/conferences/coastal2003/index.cfm.

  • Ecohazard 2003 IWA Conference. This conference will occur September 14-17 in Aachen, Germany. Environmentally toxic substances, such as DNA-damaging chemicals, heavy metals and other pollutants still pose many questions and await new solutions. This conference provides the best opportunity for exchanging scientific knowledge and recent views on the topics among scientists and administrators. Ecohazard 2003 will include presentations by leading scientists and policy makers of national and international organizations. For more information, visit http://www.ecohazard2003.rwth-aachen.de/main.html.

  • Second International Conference on the Remediation of Contaminated Sediments - The Second International Sediment Remediation Conference will be held in September 30th through October 3rd in Venice, Italy. Organizers say the city is an ideal setting for a conference on this topic because of the sediments remediation efforts being exerted there by the local, regional, and national governments. For more information, contact the Conference Group at 800-783-6338 (U.S. and Canada) or 614-488-2030; e-mail: info@confgroupinc.com; or visit the Sediment Remediation Conference website.

  • Contaminated Soils, Sediments, and Water. The conference is from October 20-23 in Amherst, MA. For more information, contact Denise Leonard at 413-545-1239 or info@UMassSoils.com. Web site: www.umasssoils.com.

  • U.S. Section PIANC Annual Meeting. This meeting is in Portland, OR, occurring October 28-30. Roundtable on Protecting America's Ports from Natural and Man-made Disasters. Technical Workshops On Wetlands Restoration and Passing Vessel Issues.  Web site: http://www.iwr.usace.army.mil/PIANC/home1.htm

  • SETAC 24th Annual Meeting: Science Without Borders: Developing Solutions for Global Environmental Challenges. This meeting takes place November 8-13 in Austin, TX. This conference supports efforts scientists and engineers to work together to develop solutions to global problems. Topics including the factors influencing bioavailability and sediment chemistry will be addressed. For more information, contact SETAC North America, 1010 North 12th Avenue, Pensacola, FL 32501. Phone: 850-469-1500; website: http://setac.org/austin.html.

  • Specialist Dredging Techniques, Inspiring Dredging Solutions. This conference occurs November 20-21 in Amsterdam, The Netherlands. The Central Dredging Association has programmed this conference to present a state of the art review of specialized dredging techniques and innovative approaches to individual dredging operations. The conference addresses techniques for core business but also from the so-called niche applications. The aim is to discuss and share ideas and to initiate the exchange of experience and technology. For more information, visit http://www.dredging.org and click on the Dredging Days 2003 link.

  • 14th Annual West Coast Confrence on Soil, Sediment, and Water. The conference is March 15-18, 2004 in San Diego, CA. The workshop will offer attendees an opportunity to exchange findings, ideas, and recommendations in a professional setting. The strong and diverse technical program has been developed to meet the changing needs of the environmental field. For more information, visit http://www.aehs.com/conferences/westcoast/index.htm or contact Brenna Bartell at 413-549-5170 or e-mail brenna@aehs.com.

  • Watersheds 2004. This conference takes place July 11-14, 2004 in Dearborn, Michigan. For more information visit http://environment.harvard.edu/lists/archives/envconfs-l/msg01994.html or contact Water Environment Federation, 601 Wythe Street, Alexandria, VA 22314-1994. Phone: 703-684-2400 x7010; fax: 703-684-2413; e-mail: watershed 04@wef.org.

  • Coastal Structures Conference. The meeting occurs July 26-29, 2004 in Portland, Oregon. This conference will offer a forum to discuss the following topics: functional and structural design; rubble mound breakwaters, revetments, jetties; shore protection structures; caisson breakwaters; innovative structures; wave-structure interaction; physical modeling; geotechnical design and performance; and many other subjects, including dredge disposal caps/environmental containment. For more information, contact the American Society of Civil Engineers, World Headquarters, 1801 Alexander Bell Drive Reston, Virginia 20191-4400. Phone: 800-548-2723 or 703-295-6300 or visit http://www.asce.org/conferences/coastal2003/index.cfm.

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Websites of Interest

All weblinks will exit EPA exit EPA

EnviroTools. This website is a personal guide to involve a community in the cleanup of a polluted site. The site provides a collection of educational materials on Superfund and Brownfields sites, along with sites cleaned up under state programs. www.envirotools.org/factsheets/contaminatedsediments.shtml

Chesapeake Ecotox Research Program (CERP). CERP is a multi-institutional program that will develop a means for predicting the effects of contaminant reduction strategies on living resources in the Chesapeake Bay. The long-range aims of this five-year collaborative project by scientists from the University of Maryland Center for Environmental Studies UMCES), the Virginia Institute of Marine Science (VIMS), the Academy of Natural Sciences Estuarine Research Center (ANSERC) and Old Dominion University (ODU) - all of which are members of the Chesapeake Research Consortium (CRC) - are to quantify how low, but chronic levels of pollutants affect ecologically important Bay species. www.mdsg.umd.edu/CERP/index.html

Coast Alliance. The Coast Alliance is a non-profit organization that was formed to increase public awareness of the coast's immense value, to bring new and important scientific facts about coastal ecology to public attention, to encourage groups across the country to work to protect valuable coastal resources, and to urge federal, state and local governments to strengthen policies and programs to protect coastal ecosystems and habitats. The Coast Alliance works with more than 500 state, local, and national organizations dedicated to preserving our ocean and coasts. The Coast Alliance provides outreach and technical support to these groups, and focuses on three major coastal problems: polluted runoff, coastal development, and contaminated underwater sediments. http://www.coastalliance.org

SedWebSM is an online community designed to promote improvements in contaminated sediments management and research. This web site is sponsored by the South and Southwest region of the Hazardous Substance Research Centers (HSRC), a five-center consortium established and supported by the U.S. Environmental Protection Agency. www.sediments.org

 

 

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